Question 34

Q35Short answer

How would you explain the fact that first ionisation enthalpy of sodium is lower than that of magnesium but its second ionisation enthalpy is higher than that of magnesium?

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After removing 1 electron from the sodium atom the ion formed acquires the configuration of inert gas, neon. The second electron is removed from one of the 2p-orbitals which are completely filled i.e., have a total of 6 electrons and are closer to the nucleus. 37 Classification of Elements and Periodicity in Properties