Question 34

Q34Short answer

CuSO4.5H2O is blue in colour while CuSO4 is colourless. Why?

Show answer

In CuSO4.5H2O, water acts as ligand as a result it causes crystal field splitting. Hence d—d transition is possible in CuSO4.5H2O and shows colour. In the anhydrous CuSO4 due to the absence of water (ligand), crystal field splitting is not possible and hence no colour.